Liquid Structure of 1-Butyl-3-methylimidazolium Hexafluorophosphate by Neutron Diffraction with H/D Isotopic Substitution Method

• KANAKUBO Mitsuhiro

  National Institute of Advanced Industrial Science and Technology (AIST)

• IKEDA Takuji

  National Institute of Advanced Industrial Science and Technology (AIST)

• AIZAWA Takafumi

  National Institute of Advanced Industrial Science and Technology (AIST)

• NANJO Hiroshi

  National Institute of Advanced Industrial Science and Technology (AIST)

• KAMEDA Yasuo

  Department of Material and Biological Chemistry, Faculty of Science, Yamagata University

• AMO Yuko

  Department of Material and Biological Chemistry, Faculty of Science, Yamagata University

• USUKI Takeshi

  Department of Material and Biological Chemistry, Faculty of Science, Yamagata University

Abstract

The liquid structure of the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate, [BMIM]PF₆, was investigated by neutron diffraction with H/D substitution method, where the hydrogen atoms in the imidazolium ring were partially deuterated. The local structures around the ring hydrogen atoms in liquid are very similar to those estimated from the crystal structure.

Journal

• Analytical Sciences

  Analytical Sciences 24 (10), 1373-1376, 2008

  The Japan Society for Analytical Chemistry

Keywords

• Analytical Chemistry

Details

• CRID: 1390001204257567744
• NII Article ID: 10025207738
• NII Book ID: AA10500785
• DOI: 10.2116/analsci.24.1373
• ISSN: 13482246
• ISSN: 09106340
• NDL BIB ID: 9667531
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I9667531
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.24.1373.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.24.1373/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/24/10/24_10_1373/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed