Synthesis of Substituted Aromatic Compounds Using Ruthenium-Catalyzed Ring-Closing Metathesis

• Yoshida Kazuhiro

  Graduate School of Science, Chiba University

• Imamoto Tsuneo

  Graduate School of Science, Chiba University

• Yanagisawa Akira

  Graduate School of Science, Chiba University

Bibliographic Information

Other Title

• 閉環メタセシスを利用する置換芳香族化合物の合成
• ヘイカン メタセシス オ リヨウ スル チカン ホウコウゾク カゴウブツ ノ ゴウセイ

Abstract

The demand for functionalized aromatic compounds is growing rapidly in many research fields. Therefore, the efficient synthesis of desired aromatic compounds is a critical issue in organic synthesis. In this account, we describe new synthetic approaches to versatile aromatic compounds, such as phenols, benzenes, 3-hydroxypyridines, and styrenes, by ring-closing olefin metathesis (RCM)/aromatization and ring-closing enyne metathesis (RCEM)/aromatization of acyclic precursors. The advantages in terms of simplicity, flexibility, and avoidance of the formation of regioisomers are proof of the versatility of this method for the synthesis of aromatic compounds.

Journal

• Journal of Synthetic Organic Chemistry, Japan

  Journal of Synthetic Organic Chemistry, Japan 67 (9), 876-888, 2009

  The Society of Synthetic Organic Chemistry, Japan

Keywords

• aromatic compound
• aromatization
• carbon-carbon bond formation
• elimination
• isomerization
• ring-closing metathesis
• ruthenium catalyst
• tautomerization

Details

• CRID: 1390001205312086144
• NII Article ID: 10025399994
• NII Book ID: AN0024521X
• DOI: 10.5059/yukigoseikyokaishi.67.876
• COI: 1:CAS:528:DC%2BD1MXht1WgtLnO
• ISSN: 18836526
• ISSN: 00379980
• NDL BIB ID: 10384759
• Web Site: http://id.ndl.go.jp/bib/10384759
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I10384759
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed