Relationship between cage occupations of guest molecules in gas hydrates encaging methane mixtures and gas compositions
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- KIDA Masato
- Methane Hydrate Research Center, National Institute of Advanced Industrial Science and Technology
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- SAKAGAMI Hirotoshi
- Department of Materials Science and Engineering, Kitami Institute of Technology
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- TAKAHASHI Nobuo
- Department of Materials Science and Engineering, Kitami Institute of Technology
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- KAMATA Yasushi
- Methane Hydrate Research Center, National Institute of Advanced Industrial Science and Technology
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- OYAMA Hiroyuki
- Methane Hydrate Research Center, National Institute of Advanced Industrial Science and Technology
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- TAKEYA Satoshi
- Research Institute of Instrumentation Frontier, National Institute of Advanced Industrial Science and Technology (AIST)
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- EBINUMA Takao
- Methane Hydrate Research Center, National Institute of Advanced Industrial Science and Technology
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- NARITA Hideo
- Methane Hydrate Research Center, National Institute of Advanced Industrial Science and Technology
Bibliographic Information
- Other Title
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- メタンを含む混合ガスハイドレートのゲスト分子の ケージ占有性とガス組成の関係
- メタン オ フクム コンゴウ ガスハイドレート ノ ゲスト ブンシ ノ ケージ センユウセイ ト ガス ソセイ ノ カンケイ
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Abstract
In this study, the cage occupations of guest molecules in gas hydrates formed from methane-carbon dioxide, methane-ethane, and methane-propane mixtures are estimated using cross-polarization magic angle spinning carbon-13 nuclear magnetic resonance (CP-MAS 13C NMR) technique. The 13C chemical shifts of the guest molecules depended on the type of hydrate cage. The cage occupations of two guest components were estimated from the integrated intensity ratio of the obtained NMR signals. In the methane and carbon dioxide system, the number of methane molecules in the large cages of structure I tended to decrease with an increase in the concentration of carbon dioxide as a second component. On the other hand, in the methane-ethane and methane-propane systems, the large cages were predominantly occupied by C2H6 or C3H8 rather than CH4 molecules. The cage occupancies of methane-ethane and methane-propane gas hydrates were almost full in the case of large cages, but a few small cages remained vacant.
Journal
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- Journal of the Japanese Society of Snow and Ice
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Journal of the Japanese Society of Snow and Ice 71 (5), 329-339, 2009
The Japanese Society of Snow and Ice
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Details 詳細情報について
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- CRID
- 1390287629000019840
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- NII Article ID
- 10025591431
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- NII Book ID
- AN00131221
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- ISSN
- 18836267
- 03731006
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- NDL BIB ID
- 10438787
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed