Scalar Order in PrFe<SUB>4</SUB>P<SUB>12</SUB> Studied by Thermal Expansion and Magnetostriction

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  • Scalar order in PrFe4P12 studied by thermal expansion and magnetostriction

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Abstract

We present the results of high-resolution measurements of the thermal expansion and magnetostriction of the cubic filled skutterudite compound PrFe4P12. The temperature dependence of the thermal expansion ΔL(T)⁄L for the three main symmetry directions are nearly identical below TA, in accordance with a recently proposed scalar order parameter for the A-phase. In the field-angle dependence of the transverse thermal expansion ΔL(θ)⁄L along the [001] direction (θ is the angle between the [100] direction and the orientation of a magnetic field within the (001) plane), we find clear twofold oscillation. On the basis of mean-field analyses, we show that the observed twofold oscillation can be interpreted as the the crystal field effect for the cubic Th symmetry. Our results suggest that the crystal field scheme consists of a Γ1 ground state and a Γ4(1) first-excited state, in both the non-ordered and A-phases.

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