Phase Formation and Solidification Routes Near Mo-Mo<SUB>5</SUB>SiB<SUB>2</SUB> Eutectic Point in Mo-Si-B System
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- Ha Seong-Ho
- Graduate School of Environmental Studies, Tohoku University
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- Yoshimi Kyosuke
- Graduate School of Environmental Studies, Tohoku University
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- Maruyama Kouichi
- Graduate School of Environmental Studies, Tohoku University
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- Tu Rong
- Institute for Materials Research, Tohoku University
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- Goto Takashi
- Institute for Materials Research, Tohoku University
Bibliographic Information
- Other Title
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- Phase formation and solidification routes near Mo-Mo5SiB2 eutectic point in Mo-Si-B system
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Abstract
The phase formation behavior during solidification in the Mo-Si-B system was experimentally examined around the triple junction point (T) of the Mo solid solution (Moss), Mo5SiB2 (T2) and Mo2B primary phases in the Mo-Si-B liquidus projection suggested by Yang and Chang through thermodynamic calculations, and the solidification routes of the Mo-Si-B alloys were reconsidered based on the obtained results. Alloys of four different compositions around the T point were produced by arc-melting. The primary phases observed in these alloys were in excellent agreement with the liquidus projection proposed by Yang and Chang. The solidification routes were basically Moss (primary) → Moss + Mo2B → Moss + T2 eutectic → Moss + T2 + Mo3Si (A15), T2 (primary) → Moss + T2 eutectic → Moss + T2 + A15, or Mo2B (primary) → Moss + T2 eutectic → Moss + T2 + A15, depending on the composition. However, a quantitative EPMA analysis indicated the compositions of the Moss-T2 eutectic and Moss + T2 + A15 phases differed from the reported liquidus projection. This is due to the difficulties interpreting the unusual solidification routes in the Mo-Si-B system and their as-cast microstructures.
Journal
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- MATERIALS TRANSACTIONS
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MATERIALS TRANSACTIONS 51 (9), 1699-1704, 2010
The Japan Institute of Metals and Materials
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Details 詳細情報について
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- CRID
- 1390282679227786624
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- NII Article ID
- 10026600350
- 130004454561
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- NII Book ID
- AA1151294X
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- ISSN
- 13475320
- 13459678
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- NDL BIB ID
- 10803367
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed