Hydrogen peroxide formation on several carbon materials in sulfuric acid solution

• Kinumoto Taro

  Department of Applied Chemistry, Oita University

• Nakamura Junichi

  Department of Materials Science, The University of Shiga Prefecture

• Kikuchi Kenji

  Department of Materials Science, The University of Shiga Prefecture

• Ogumi Zempachi

  Department of Energy & Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University

抄録

Hydrogen peroxide (H₂O₂) formation on Ketjen blackR EC300J, Vulcan XC-72R® and acetylene black in sulfuric acid solution was investigated. For this purpose, an ultra-microanalysis system for H₂O₂ was constructed. It was clarified that H₂O₂ was produced through an oxygen reduction reaction on these carbon materials. When oxidized acetylene blacks were employed, both the content of alcohol-like groups and the amounts of H₂O₂ produced increased. It is, therefore, surmised that the alcohol-like groups on acetylene blacks mainly contribute to H₂O₂ formation in a similar manner as the so-called “anthraquinone process”, the practical method for H₂O₂ production.

収録刊行物

• 炭素

  炭素 2010 (244), 143-146, 2010

  炭素材料学会

キーワード

• Carbon black
• Hydrogen peroxide
• Oxygen reduction reaction

詳細情報

• CRID: 1390282679202985728
• NII論文ID: 10026612473
• NII書誌ID: AN00140335
• DOI: 10.7209/tanso.2010.143
• ISSN: 18845495
• ISSN: 03715345
• NDL書誌ID: 10827714
• Web Site: http://id.ndl.go.jp/bib/10827714
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I10827714
• 本文言語コード: en
• データソース種別:
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  • NDL
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  • KAKEN
• 抄録ライセンスフラグ: 使用不可