Weak Binding of N-Alkylpyridinium Ions to Nonionic Surfactant Micelles as Studied by Capillary Zone Electrophoresis

• TAKAYANAGI Toshio

  Department of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University

• IKUTA Ayumi

  Department of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University

• MOTOMIZU Shoji

  Department of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University

Abstract

The binding equilibrium of N-alkylpyridinium ions to nonionic surfactant micelles was investigated through the changes in the electrophoretic mobility of the alkylpyridinium ions in capillary zone electrophoresis. The binding constants thus determined increased with increasing molecular volume of the alkylpyridinium ions. However, the binding constants are small compared with the ones for the anionic alkylbenzenesulfonate and polynitrophenolate ions at the same molecular volume.

Journal

• Analytical Sciences

  Analytical Sciences 26 (5), 625-627, 2010

  The Japan Society for Analytical Chemistry

Keywords

• Analytical Chemistry

Details

• CRID: 1390001204256463744
• NII Article ID: 130004441985
• NII Article ID: 10026783806
• NII Book ID: AA10500785
• DOI: 10.2116/analsci.26.625
• ISSN: 13482246
• ISSN: 09106340
• NDL BIB ID: 10668241
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I10668241
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.26.625.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.26.625/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/26/5/26_5_625/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed