MnIII Salen-type Single-molecule Magnet Fixed in a Two-dimensional Network

• Chihiro Kachi-Terajima

  Department of Chemistry, Faculty of Science, Toho University

• Erina Mori

  Department of Chemistry, Faculty of Science, Toho University

• Tasuku Eiba

  Department of Chemistry, Faculty of Science, Toho University

• Toshiaki Saito

  Department of Physics, Faculty of Science, Toho University

• Chikahide Kanadani

  Research Center for Materials with Integrated Properties, Toho University

• Takafumi Kitazawa

  Department of Chemistry, Faculty of Science, Toho University

• Hitoshi Miyasaka

  Department of Chemistry, Graduate School of Science, Tohoku University

抄録

A two-dimensional network compound, [{Mn(saltmen)}4{Co(CN)6}](ClO4)·9H2O (2) (saltmen2− = N,N′-(1,1,2,2-tetramethylethylene)bis(salicylideneiminate)), was synthesized. Magnetic measurements characterized the [Mn2(saltmen)2]2+ subunit as a single-molecule magnet with an ST = 4 spin ground state, indicating that the MnIII dimer is magnetically isolated not only by the diamagnetic [Co(CN)6]3− unit but also by the space between the layers.

収録刊行物

• Chemistry Letters

  Chemistry Letters 39 (2), 94-95, 2009-12-26

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360283694088178432
• NII論文ID: 10027176953
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2010.94
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/39/2/94/55601161/cl.2010.94.pdf
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