An Acid-stable Organoruthenium Complex Suitable as a Bidentate Building Block

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  • Chunbai Zheng
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
  • Daisuke Inoki
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
  • Takahiro Matsumoto
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
  • Seiji Ogo
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University

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<jats:title>Abstract</jats:title> <jats:p>A new, water-soluble organoruthenium(II) sulfato complex [RuII(SO4)(Bz^py)] {1, Bz^py = 2-(pentamethylbenzyl)pyridine} has been synthesized and is stable at pH from 2.0 to 8.0. This complex has a bidentate sulfato ligand as a leaving group and is a good building block for “concerto catalysis”: a new way of thinking in catalysis that bridges hetero- and homogeneous catalysis.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 39 (2), 130-131, 2010-01-16

    Oxford University Press (OUP)

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