One-dimensional Tube-like {51262}<i>n</i> Water Clusters Stabilized in a Molecular Nanoporous Framework

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  • Makoto Tadokoro
    Department of Chemistry, Faculty of Science, Tokyo University of Science
  • Chihiro Iida
    Department of Chemistry, Faculty of Science, Tokyo University of Science
  • Takahito Saitoh
    Department of Chemistry, Faculty of Science, Tokyo University of Science
  • Takahiro Suda
    Department of Chemistry, Faculty of Science, Tokyo University of Science
  • Yuji Miyazato
    Department of Chemistry, Faculty of Science, Tokyo University of Science

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<jats:title>Abstract</jats:title> <jats:p>Water nanotube clusters (WNTs) contained in nanochannels of molecular porous crystal are prepared. The structure of these WNT is almost the same as that of partial clathrate-hydrate type-I, which is constructed from 1-D {51262}n water clusters stabilized under ambient atmosphere. The WNT has a structural phase transition at −53.5 °C from the solid to liquid state.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 39 (3), 186-187, 2010-01-30

    Oxford University Press (OUP)

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