Hg(OTf)2-catalyzed Cycloisomerization of Aryl- and Hetero-substituted 1,3-Dienes

• Yamamoto Hirofumi

  Faculty of Pharmaceutical Sciences, Tokushima Bunri University

• Shiomi Shinya

  Faculty of Pharmaceutical Sciences, Tokushima Bunri University

• Odate Daiki

  Faculty of Pharmaceutical Sciences, Tokushima Bunri University

• Sasaki Ikuo

  Faculty of Pharmaceutical Sciences, Tokushima Bunri University

• Namba Kosuke

  Faculty of Pharmaceutical Sciences, Tokushima Bunri University

• Imagawa Hiroshi

  Faculty of Pharmaceutical Sciences, Tokushima Bunri University

• Nishizawa Mugio

  Faculty of Pharmaceutical Sciences, Tokushima Bunri University

抄録

We developed Hg(OTf)₂-catalyzed Friedel–Crafts-like cycloisomerization of 7-arylhepta-1,3-dienes to give propenyl-substituted tetrahydronaphthalenes in excellent catalytic turnover under very mild conditions. 1,3-Dienyl sulfonamides and 1,3-dienyl alcohols were also efficiently cyclized to afford heterocyclic compounds.

収録刊行物

• Chemistry Letters

  Chemistry Letters 39 (8), 830-831, 2010

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390001204584263040
• NII論文ID: 10027183656
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2010.830
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/39/8/830/55602421/cl.2010.830.pdf
• 本文言語コード: en
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