Poly-<scp>l</scp>-lysine-induced Self-association and Luminescence of Dicyanoaurate(I)

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  • Toshiyuki Moriuchi
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University
  • Kazuki Yoshii
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University
  • Chiaki Katano
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University
  • Toshikazu Hirao
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University

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<jats:title>Abstract</jats:title> <jats:p>The assembling and self-association of anionic [Au(CN)2]− spatially along cationic β-sheeted poly-l-lysine, P(Lys), through electrostatic interaction was demonstrated to form luminescent [Au(CN)2]− aggregates, wherein negatively charged [Au(CN)2]− was found to stabilize the β-sheet structure by suppressing repulsion between the positively charged side chains.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 39 (8), 841-843, 2010-07-03

    Oxford University Press (OUP)

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