Acetylated Cyclodextrins as New Organogelators

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  • Toshiyuki Kida
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University
  • Koichiro Kishimoto
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology
  • Koji Hatano
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology
  • Masahiro Muraoka
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology
  • Yohji Nakatsuji
    Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology
  • Mitsuru Akashi
    Department of Applied Chemistry, Graduate School of Engineering, Osaka University

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<jats:title>Abstract</jats:title> <jats:p>Acetylated cyclodextrins (CDs), including peracetylated α- and β-CDs as well as 2,3-O-diacetylated α- and β-CDs, were found to function as organogelators for organic solvents such as benzene, toluene, and xylenes at ambient temperature. Their organogelation capability was strongly affected by both the CD ring size and the degree of acetylation. Peracetylated α-CD showed the highest organogelation capability among these acetylated CDs, possibly due to the effective construction of three-dimensional networks by the pillar-like assemblies in the organic solvents.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 39 (11), 1206-1208, 2010-10-20

    Oxford University Press (OUP)

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