Ferromagnetic Gd–Cu, Tb–Cu, and Ho–Cu Couplings in Isomorphous [Ln2Cu] Complexes

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  • Atsushi Okazawa
    Department of Engineering Science, The University of Electro-Communications
  • Ryo Watanabe
    Department of Engineering Science, The University of Electro-Communications
  • Masaru Nezu
    Department of Engineering Science, The University of Electro-Communications
  • Takashi Shimada
    Department of Engineering Science, The University of Electro-Communications
  • Shunsuke Yoshii
    Institute for Materials Research, Tohoku University
  • Hiroyuki Nojiri
    Institute for Materials Research, Tohoku University
  • Takayuki Ishida
    Department of Engineering Science, The University of Electro-Communications

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<jats:title>Abstract</jats:title> <jats:p>Exchange couplings in [{Ln(hfac)3}2Cu(dpk)2] (Hdpk stands for di-2-pyridyl ketoxime) were evaluated by high-frequency electron paramagnetic resonance and magnetization studies, showing ferromagnetic Ln–Cu couplings with JLn–Cu/kB = +1.271(7), +0.405(3), and +0.196(13) K for Ln: Gd, Tb, and Ho, respectively.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 39 (12), 1331-1332, 2010-11-20

    Oxford University Press (OUP)

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