Stereoselective Construction of Tetra-Substituted Tetrahydrofuran Compounds from Benzylic Hemiacetal in the Presence of H₂and a Pd Catalyst: Stereoselective Synthesis of a Stereoisomer of (−)-Virgatusin and Its Antimicrobiological Activity

• NAKATO Tomofumi

  Faculty of Agriculture, Ehime University

• TAGO Ryosuke

  Faculty of Agriculture, Ehime University

• AKIYAMA Koichi

  Integrated Center for Sciences, Tarumi Station, Ehime University

• MARUYAMA Masafumi

  Faculty of Agriculture, Ehime University

• SUGAHARA Takuya

  Faculty of Agriculture, Ehime University

• KISHIDA Taro

  Faculty of Agriculture, Ehime University

• YAMAUCHI Satoshi

  Faculty of Agriculture, Ehime University

書誌事項

タイトル別名

• Stereoselective Construction of Tetra-Substituted Tetrahydrofuran Compounds from Benzylic Hemiacetal in the Presence of H2 and a Pd Catalyst: Stereoselective Synthesis of a Stereoisomer of (-)-Virgatusin and Its Antimicrobiological Activity

抄録

Tetra-substituted tetrahydrofuran compounds were stereoselectively prepared from benzylic hemiacetal in the neutral condition by employing the simple reagent, H₂, and a Pd catalyst. The stereoselective conversion of benzylic hemiacetal to two different stereoisomers of the tetrasubstituted tetrahydrofuran compound was observed. One of these tetrahydrofuran compounds was converted to the virgatusin stereoisomer to estimate its antimicrobiological activity.

収録刊行物

• Ｂｉｏｓｃｉｅｎｃｅ，　Ｂｉｏｔｅｃｈｎｏｌｏｇｙ，　ａｎｄ　Ｂｉｏｃｈｅｍｉｓｔｒｙ

  Ｂｉｏｓｃｉｅｎｃｅ，　Ｂｉｏｔｅｃｈｎｏｌｏｇｙ，　ａｎｄ　Ｂｉｏｃｈｅｍｉｓｔｒｙ 72 (1), 197-203, 2008

  公益社団法人 日本農芸化学会

キーワード

• virgatusin
• tetrahydrofuran lignan
• antimicrobiological activity

詳細情報

• CRID: 1390001206478180096
• NII論文ID: 10027523396
• NII書誌ID: AA10824164
• DOI: 10.1271/bbb.70554
• ISSN: 13476947
• ISSN: 09168451
• NDL書誌ID: 9365287
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I9365287
• Web Site: http://www.tandfonline.com/doi/pdf/10.1271/bbb.70554
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可