Synthesis and Properties of Functional π-Expanded Compounds Prepared by Thermal or Photochemical Conversion of the Precursors

DOI Web Site Web Site 1 Citations 177 References
  • Yamada Hiroko
    Graduate School of Material Science, Nara Institute of Science and Technology JST, CREST
  • Kuzuhara Daiki
    Graduate School of Material Science, Nara Institute of Science and Technology
  • Katsuta Shuhei
    Graduate School of Material Science, Nara Institute of Science and Technology
  • Okujima Tetsuo
    Graduate School of Science and Engineering, Ehime University
  • Uno Hidemitsu
    Graduate School of Science and Engineering, Ehime University

Bibliographic Information

Other Title
  • 前駆体法を利用した機能性π共役拡張化合物の合成と物性
  • ゼンクタイホウ オ リヨウ シタ キノウセイ パイ キョウヤク カクチョウ カゴウブツ ノ ゴウセイ ト ブッセイ
  • Synthesis and Properties of Functional π-Expanded Compounds Prepared by Thermal or Photochemical Conversion of the Precursors

Search this article

Abstract

This paper focuses on the synthesis of new aromatic compounds by thermal, photochemical, or oxidative cleavage reaction of the corresponding precursors. The precursor-methods are useful for the derivatization of the non-soluble aromatic compounds. We have applied retro Diels-Alder reactions for the preparation of new π-expanded porphyrinoid compounds such as [14]tribenzotriphyrin(2.1.1), tetrabenzoporphycene, dodecasubstituted porphycene, tetraanthraporphyin, butadiyne-linked tetrabenzoporphyrin dimer, and so on. We have investigated the photocleavage synthesis of pentacenes from the corresponding α-diketone precursors. This photoreaction enabled us to prepare 1,4,8,11-tetrasubstituted pentacene. The synthesis of new pentacene derivatives with electron-withdrawing substituents at 6,13-positions by oxidative cleavage reaction will be also reported.

Journal

Citations (1)*help

See more

References(177)*help

See more

Related Projects

See more

Keywords

Details 詳細情報について

Report a problem

Back to top