Iron-catalyzed Oxidative Coupling of Alkylamines with Arenes, Nitroalkanes, and 1,3-Dicarbonyl Compounds

  • Eiji Shirakawa
    Department of Chemistry, Graduate School of Science, Kyoto University
  • Tomoki Yoneda
    Department of Chemistry, Graduate School of Science, Kyoto University
  • Kohei Moriya
    Department of Chemistry, Graduate School of Science, Kyoto University
  • Kensuke Ota
    Department of Chemistry, Graduate School of Science, Kyoto University
  • Nanase Uchiyama
    Department of Chemistry, Graduate School of Science, Kyoto University
  • Ryo Nishikawa
    Department of Chemistry, Graduate School of Science, Kyoto University
  • Tamio Hayashi
    Department of Chemistry, Graduate School of Science, Kyoto University

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<jats:title>Abstract</jats:title> <jats:p>FeCl3 in combination with t-BuOOt-Bu as an oxidant was found to catalyze oxidative coupling of alkylamines with arenes, nitroalkanes, and 1,3-dicarbonyl compounds to give arylmethylamines, β-nitroalkylamines, and 2-(aminomethyl)-1,3-dicarbonyl compounds, respectively.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 40 (9), 1041-1043, 2011-09

    Oxford University Press (OUP)

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