Intercalation of sodium into graphite-like layered material BC2N

• Yamada Kaoru

  Graduate School of Engineering, Osaka Electro-Communication University

• Kurasaki Akihiro

  Graduate School of Engineering, Osaka Electro-Communication University

• Kawaguchi Masayuki

  Graduate School of Engineering, Osaka Electro-Communication University Fundamental Electronics Research Institute, Osaka Electro-Communication University

Bibliographic Information

Other Title

• グラファイト様層状化合物BC2Nへのナトリウムのインターカレーション
• グラファイト ヨウ ソウジョウ カゴウブツ BC2N エ ノ ナトリウム ノ インターカレーション

Abstract

Graphite-like layered material of composition BC₂N was prepared by the CVD reaction of acetonitrile with boron trichloride at 2070 K. Sodium was intercalated into the BC₂N film and powder by two methods: a vapor phase reaction and an electrochemical method. The first stage compounds were prepared by the vapor phase reaction using the BC₂N film and powder. A mixture of the first and the second stage compounds was prepared from the BC₂N powder, while the first stage compound was prepared from the BC₂N film by the electrochemical method. The d-spacing of the intercalated layers was 0.43 nm, calculated from the sharp (001) and (002) diffraction lines observed on the X-ray diffraction patterns of the first stage compounds prepared from the BC₂N films by the two methods.

Journal

• TANSO

  TANSO 2011 (249), 161-167, 2011

  THE CARBON SOCIETY OF JAPAN

Keywords

• Carbon alloy
• B/C/N material
• Intercalation compound
• Sodium

Details

• CRID: 1390001204226472960
• NII Article ID: 10029546832
• NII Book ID: AN00140335
• DOI: 10.7209/tanso.2011.161
• ISSN: 18845495
• ISSN: 03715345
• NDL BIB ID: 11229013
• Web Site: http://id.ndl.go.jp/bib/11229013
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I11229013
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed