Radii of Microelectrodes Undervalued from Steady-state Currents

• Koichi Aoki

  Department of Applied Physics, University of Fukui

• Haruki Takeuchi

  Department of Applied Physics, University of Fukui

• Jingyuan Chen

  Department of Applied Physics, University of Fukui

• Toyohiko Nishiumi

  Department of Applied Physics, University of Fukui

書誌事項

タイトル別名

• Radii of microelectrodes undervalued from steady-state currents

抄録

We examined Saito's equation for diffusion-controlled current at a microdisk electrode. We measured steady-state currents of a ferrocenyl derivative at glass-coated Pt electrodes with various sizes, of which radii were evaluated with a scanning electron microscope. The relation between the currents and the radii less than 2 μm deviated downward from the proportionality, whereas the proportionality was maintained accurately for the radii more than 5 μm. Radii of invisible electrodes which have been so far evaluated from the steady-state currents should be smaller than the geometrical values. The lower deviation of the proportionality was explained in terms of memory diffusion of the Fick's first law under the steady state.

収録刊行物

• Ｒｅｖｉｅｗ　ｏｆ　Ｐｏｌａｒｏｇｒａｐｈｙ

  Ｒｅｖｉｅｗ　ｏｆ　Ｐｏｌａｒｏｇｒａｐｈｙ 57 (2), 101-119, 2011

  日本ポーラログラフ学会

キーワード

• General Earth and Planetary Sciences
• General Environmental Science

詳細情報

• CRID: 1390282681548328320
• NII論文ID: 10029678128
• NII書誌ID: AA00817694
• DOI: 10.5189/revpolarography.57.101
• ISSN: 18847692
• ISSN: 00346691
• NDL書誌ID: 11267619
• Web Site: http://id.ndl.go.jp/bib/11267619
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I11267619
• 本文言語コード: en
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