Redox Reaction of Bis(dithiolene)sulfidotungsten(IV) Complex with Elemental Sulfur: Functional Analogs of Polysulfide Reductase of Molybdoenzymes
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- Hideki Sugimoto
- Department of Material and Life Science, Graduate School of Engineering, Osaka University
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- Reiko Tajima
- Department of Chemistry, Graduate School of Science, Osaka City University
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- Kazuo Toyota
- Department of Chemistry, Graduate School of Science, Osaka City University
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- Hiroyuki Miyake
- Department of Chemistry, Graduate School of Science, Osaka City University
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- Shinobu Itoh
- Department of Material and Life Science, Graduate School of Engineering, Osaka University
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<jats:title>Abstract</jats:title> <jats:p>The reaction of bis(dithiolene)sulfidotungsten(IV) complex with elemental sulfur yielded bis(dithiolene)(tetrasulfido)tungsten(IV) complex. A labeling experiment using 34S has indicated that the reaction is reversible and a sulfido(trisulfido)tungsten(VI) species is involved as an intermediate. The reaction represents a model reaction of polysulfide reductase of molybdoenzymes.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 40 (10), 1146-1148, 2011-09-28
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360002219111488256
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- NII論文ID
- 10029683426
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- NII書誌ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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