Electrochemical Control of Threshold Value of Molecular Valve Consisting of Poly(acrylic acid) Gel

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  • Kazutake Takada
    Graduate School of Engineering, Nagoya Institute of Technology
  • Tetsuya Ohara
    Graduate School of Engineering, Nagoya Institute of Technology
  • Kouki Takeue
    Graduate School of Engineering, Nagoya Institute of Technology
  • Natsumi Ishikura
    Graduate School of Engineering, Nagoya Institute of Technology
  • Chie Kato
    Graduate School of Engineering, Nagoya Institute of Technology
  • Akio Yuchi
    Graduate School of Engineering, Nagoya Institute of Technology

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<jats:title>Abstract</jats:title> <jats:p>A molecular valve, consisting of a poly(acrylic acid) gel-coated Au mesh and a Au mesh working electrode, allowed electrochemically control of a concentration where the valve opens. At open circuit and when +0.9 V vs. Ag/AgCl was applied to the Au mesh electrode, the valve opened at concentration higher than 3–4 × 10−4 M. At −0.7 V it increased to 9 × 10−4 M. On the other hand, it remained virtually constant for Ca2+ at those potentials.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 40 (10), 1152-1153, 2011-09-28

    Oxford University Press (OUP)

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