Hydrogenation of FeSi and FeS Alloys at High Pressure and High Temperature

• TERASAKI Hidenori

  Department of Earth and Space Science, Osaka University

• SHIBAZAKI Yuki

  Department of Earth and Planetary Materials Science, Tohoku University

Bibliographic Information

Other Title

• 高温高圧下におけるＦｅＳｉおよびＦｅＳ合金の水素化
• コウオン コウアツカ ニ オケル FeSi オヨビ FeS ゴウキン ノ スイソカ

Abstract

  Hydrogenation of iron-light element alloys, such as Fe-Si and Fe-S, under high pressure is important to understand the composition and the thermal structure of the planetary cores. Here, we report the hydrogenation pressures of FeSi and FeS, hydrogen solubilities into these alloys and the effect of hydrogen on their phase relations based on in situ X-ray diffraction experiment of FeSi-H and FeS-H systems up to 17 GPa and 2123 K. Hydrogenation of FeSi and FeS occurs at the pressures more than 10 GPa and 3 GPa, respectively. The H solubilities (x) are estimated to be x∼0.2-0.3, which are well below compared to the H solubility into pure iron (x∼1.0). This small amount of H solubility into the alloys causes only small depressions (150-250 K) of their melting temperaure whereas dissolution of H into Fe decreases its melting temperature significantly.<br>

Journal

• The Review of High Pressure Science and Technology

  The Review of High Pressure Science and Technology 21 (3), 197-205, 2011

  The Japan Society of High Pressure Science and Technology

Keywords

• hydrogenation
• Fe-alloy
• earth's core
• light element
• hydrogen solubility
• phase relation
• X-ray diffraction

Details

• CRID: 1390282679358493312
• NII Article ID: 10029831676
• NII Book ID: AN10452913
• DOI: 10.4131/jshpreview.21.197
• ISSN: 13481940
• ISSN: 0917639X
• NDL BIB ID: 11287069
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I11287069
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed