Highly Efficient Synthesis of Nitrogen-Atom Endohedral Fullerene by Controlling Plasma Ion Behaviors

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The thorough investigation has been made to find an optimum condition for the synthesis of the nitrogen-atom endohedral fullerene (N@C60), which contains the atomic nitrogen inside the carbon cage of C60. Using our radio-frequency-plasma apparatus, the condition is realized to maximize the density of nitrogen-molecule ions (N2+) in the plasma under the pressure of 25 Pa and the acceleration substrate bias voltage of -90 V. As a result, the target molecule of N@C60 is produced in relatively high purity (mol concentration ratio of N@C60 to C60) of 0.25%, which is an order of magnitude higher than that reported in the other literatures.

収録刊行物

  • Applied physics express

    Applied physics express 5(2), 026202-026202-3, 2012-02-25

    The Japan Society of Applied Physics

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各種コード

  • NII論文ID(NAID)
    10030155996
  • NII書誌ID(NCID)
    AA12295133
  • 本文言語コード
    EN
  • 資料種別
    SHO
  • ISSN
    18820778
  • NDL 記事登録ID
    023454542
  • NDL 請求記号
    Z78-A526
  • データ提供元
    CJP書誌  NDL  JSAP 
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