Measurement and Correlation of Liquid–Liquid Equilibria of Alcohol+Water+Alcohol Systems and Alcohol+Water+Alkane Systems

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  • Yokoyama Katsumi
    Package Development Department, Simulation Business Division, Omega Simulation Co., Ltd.
  • Matsuda Hiroyuki
    Department of Materials and Applied Chemistry, College of Science and Technology, Nihon University
  • Kurihara Kiyofumi
    Department of Materials and Applied Chemistry, College of Science and Technology, Nihon University
  • Tochigi Katsumi
    Department of Materials and Applied Chemistry, College of Science and Technology, Nihon University

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  • アルコール+水+アルコール，アルカン型3成分系液液平衡の測定と相関
  • アルコール+ミズ+アルコール,アルカンガタ 3 セイブンケイエキエキ ヘイコウ ノ ソクテイ ト ソウカン

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Abstract

Solubilities and tie line data were measured for seven ternary systems (methanol+water+n-butanol, n-propanol+water+n-butanol, n-propanol+water+n-amylalcohol, 2-propanol+water+n-amylalcohol, methanol+water+n-heptane, n-propanol+water+n-heptane, 2-propanol+water+n-heptane) using new experimental apparatus for liquid–liquid equilibria. NRTL parameters were determined using experimental tie line data and were confirmed by liquid–liquid equilibrium calculations of the components of both liquid phases from the feed components.

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