Ammonolysis of HTiNbO5–<i>n</i>-Propylamine Intercalation Compound

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  • Ammonolysis of HTiNbO5-n-Propylamine Intercalation Compound

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The ammonolysis reaction to form (Ti,Nb)N was enhanced by the use of HTiNbO5n-propylamine intercalation compound as a starting material and compared with that for a simple mixture of TiO2 and Nb2O5. The ammonolysis product formed at 1200 °C was a superconductor (Tc = 15 K) with a rock-salt crystal structure having many structural defects along the stacking direction of the intercalation compound.

収録刊行物

  • Chemistry Letters

    Chemistry Letters 40 (11), 1238-1239, 2011

    公益社団法人 日本化学会

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