197Au Mössbauer Spectroscopy of Au25(SG)18− Revisited

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  • Tatsuya Tsukuda
    Section of Catalytic Assemblies, Catalysis Research Center, Hokkaido University
  • Yuichi Negishi
    Department of Applied Chemistry, Faculty of Science, Tokyo University of Science
  • Yasuhiro Kobayashi
    Research Reactor Institute, Kyoto University
  • Norimichi Kojima
    Department of Basic Sciences, Graduate School of Arts and Sciences, The University of Tokyo

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<jats:title>Abstract</jats:title> <jats:p>Reanalysis of the 197Au Mössbauer spectrum of Au25(SG)18− (SG: glutathionate) based on the structure determined by single-crystal XRD analysis gave a reasonable fit, demonstrating that 197Au Mössbauer spectroscopy is a powerful tool for predicting the structural motifs of thiolate-protected Au clusters.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 40 (11), 1292-1293, 2011-10-26

    Oxford University Press (OUP)

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