Novel Synthetic Method for Metalloporphyrins with Inorganic Metal Salts in High-temperature Water

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著者

    • SATO Takafumi
    • Department of Material and Environmental Chemistry, Utsunomiya University
    • ITO Satoshi
    • Department of Material and Environmental Chemistry, Utsunomiya University
    • SUE Kiwamu
    • Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology
    • ITOH Naotsugu
    • Department of Material and Environmental Chemistry, Utsunomiya University

抄録

Cobalt, nickel, copper, and oxidovanadium(2+) could be incorporated into nonpolar tetraphenyl porphyrin by using feed materials as metal sulfate, nitrate, and chloride salts and reaction in high-temperature water (423 to 673 K). Yields of metalloporphyrins increased to 94% at 673 K, which indicates that the dissolution of porphyrin and reaction of the metal salts are enhanced in high-temperature water.

収録刊行物

  • Chemistry letters

    Chemistry letters 40(12), 1414-1416, 2011-12-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10030221503
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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