Diacenaphtho[1,2-b ; 1',2'-d]silole and -pyrrole

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著者

    • NAGASAKA Yoshiharu
    • Department of Materials Science and Chemistry, Graduate School of Engineering, University of Hyogo
    • KITAMURA Chitoshi
    • Department of Materials Science and Chemistry, Graduate School of Engineering, University of Hyogo
    • KURATA Hiroyuki
    • Department of Chemistry, Graduate School of Science, Osaka University
    • KAWASE Takeshi
    • Department of Materials Science and Chemistry, Graduate School of Engineering, University of Hyogo

抄録

π-Extended silole and pyrrole analogs fused with two acenaphthylene units were synthesized from 2,2′-dibromo-1,1′-biacenaphthylene. The pyrrole was obtained as a stable compound, while the silole was thermally stable, but highly acid-sensitive purple crystals. The molecular structures reveal that both heteroles have a planar π-system and stack to form a head-to-tail dimer structure. Observed electronic and electrochemical properties obviously indicate low LUMO energy level of the silole and high HOMO level of the pyrrole as predicted by DFT calculations.

収録刊行物

  • Chemistry letters

    Chemistry letters 40(12), 1437-1439, 2011-12-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10030221676
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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