Stereoselective Synthesis of Allylsilanes Bearing Tetrasubstituted Olefin via 2,2-Diborylethylsilane

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著者

    • SAKAMOTO Akira
    • Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University
    • OHKUBO Takahiro
    • Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University
    • SHIBATA Takanori
    • Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University

抄録

The regio- and stereoselective synthesis of allylsilane derivatives bearing a tetrasubstituted olefin was achieved using 2,2-diborylethylsilane as a key intermediate. The regioselective deprotonation of a 2,2-diborylethylsilane with LTMP and the subsequent nucleophilic addition to ketones gave corresponding allylsilanes in good to excellent yield with excellent stereoselectivity.

収録刊行物

  • Chemistry letters

    Chemistry letters 40(12), 1440-1442, 2011-12-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10030221712
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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