Triply Radical-coordinated Gadolinium(III) Complex as a High-spin S=5 Assembly

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著者

    • IKEGAYA Naoya
    • Department of Engineering Science, The University of Electro-Communications
    • KANETOMO Takuya
    • Department of Engineering Science, The University of Electro-Communications
    • MURAKAMI Rina
    • Department of Engineering Science, The University of Electro-Communications
    • ISHIDA Takayuki
    • Department of Engineering Science, The University of Electro-Communications

抄録

A discrete Gd<sup>3+</sup> and radical complex was prepared and characterized to be [Gd(hfac)<sub>3</sub>(HNN)<sub>3</sub>] by means of X-ray crystallographic analysis, where Hhfac stands for 1,1,1,5,5,5-hexafluoropentane-2,4-dione and HNN for 4,4,5,5-tetramethylimidazolin-1-oxyl 3-oxide. A magnetic study revealed the presence of ferromagnetic exchange coupling with 2<i>J</i>/<i>k</i><sub>B</sub> = 3.86(6) K, ascribable to the Gd–HNN interaction.

収録刊行物

  • Chemistry letters

    Chemistry letters 41(1), 82-83, 2012-01-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10030222594
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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