Benzo[<i>b</i>]trithiophene Polymer Network Prepared by Electrochemical Polymerization with a Combination of Thermal Conversion

• Takahiro Nakae

  Department of Chemistry and Biology, Graduate School of Science and Engineering, Ehime University

• Shingo Mizobuchi

  Department of Chemistry and Biology, Graduate School of Science and Engineering, Ehime University

• Maki Yano

  Department of Chemistry and Biology, Graduate School of Science and Engineering, Ehime University

• Takuya Ukai

  Institute of Advanced Energy, Kyoto University

• Hisako Sato

  Department of Chemistry and Biology, Graduate School of Science and Engineering, Ehime University

• Toru Shinmei

  Geodynamics Research Center, Ehime University

• Toru Inoue

  Geodynamics Research Center, Ehime University

• Tetsuo Irifune

  Geodynamics Research Center, Ehime University

• Hiroshi Sakaguchi

  Institute of Advanced Energy, Kyoto University

抄録

A two-step procedure of two-dimensional polymer constructed from benzo[b]trithiophene (BTT) was proposed by electrochemical polymerization and thermal conversion. Electropolymerized BTT oligomer on an electrode was thermally converted to conjugated polymer. Obtained conductive material is found to retain BTT structure by Raman spectra and to extend π conjugation by absorption spectra.

収録刊行物

• Chemistry Letters

  Chemistry Letters 41 (2), 140-141, 2012-01-28

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360283694088343936
• NII論文ID: 10030223035
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2012.140
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/41/2/140/55641328/cl.2012.140.pdf
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