Synthesis and Reactivity of a Platinum(II) Complex with Hydrosulfido Ligands Induced by a Chelated <i>N</i>-Heterocyclic Carbene Ligand

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  • Yuri Maeda
    Department of Chemistry, Graduate School of Science, Osaka City University
  • Hideki Hashimoto
    Department of Physics, Graduate School of Science, Osaka City University
  • Takanori Nishioka
    Department of Chemistry, Graduate School of Science, Osaka City University

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<jats:title>Abstract</jats:title> <jats:p>A bis(hydrosulfido)platinum(II) complex with a bidentate chelate N-heterocyclic carbene ligand was oxidized by O2 to give a linear tetrasulfide complex in the presence of excess hydrogen sulfide and a thiosulfato-bridged dinuclear complex without hydrogen sulfide.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 41 (2), 145-147, 2012-01-28

    Oxford University Press (OUP)

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