Inorganic Frameworks Made by Combining Paddle-wheel Diruthenium(II, III) Complexes and Polyoxometalate Clusters

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著者

    • SAWADA Yuki
    • Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
    • YAMAMOTO Yuma
    • Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
    • NISHIO Masaki
    • Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
    • KOSAKA Wataru
    • Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
    • HAYASHI Yoshihito
    • Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
    • MIYASAKA Hitoshi
    • Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University

抄録

The reactions of a pivalate-bridged paddle-wheel diruthenium(II, III) complex, [Ru<sub>2</sub><sup>II,III</sup>(piv)<sub>4</sub>(THF)<sub>2</sub>]BF<sub>4</sub>, with two kinds of polyoxometalates (POMs), (TBA)<sub>2</sub>[Mo<sub>6</sub>O<sub>19</sub>] and (TBA)<sub>3</sub>[H<sub>3</sub>V<sub>10</sub>O<sub>28</sub>] (TBA: tetra-<i>n</i>-butylammonium cation), led to the formation of one- and two-dimensional inorganic frameworks composed of [–{Ru<sub>2</sub>}<i><sub>n</sub></i>–(POM)–]<sup>−</sup> repeating units with <i>n</i> = 1 and 2, respectively.

収録刊行物

  • Chemistry letters

    Chemistry letters 41(3), 212-214, 2012-03-05

    公益社団法人 日本化学会

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各種コード

  • NII論文ID(NAID)
    10030223708
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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