Photoelectrochemical Reduction of Carbon Dioxide at Si(111) Electrode Modified by Viologen Molecular Layer with Metal Complex

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著者

    • SUN Yu
    • Division of Chemistry, Graduate School of Science, Hokkaido University
    • MASUDA Takuya
    • Global Research Center for Environment and Energy based on Nanomaterials Science (GREEN), National Institute for Materials Science (NIMS)
    • UOSAKI Kohei
    • Division of Chemistry, Graduate School of Science, Hokkaido University

抄録

Photoelectrochemical carbon dioxide reduction was carried out at a p-type Si(111) electrode modified with a viologen molecular layer and AuCl4^[2-] or PdCl4^[2-]. It was proven that the reduction reaction was mediated by viologen moiety and while CO2 reduction was dominant at the Si(111) electrode modified with PdCl4^[2-] in the potential region where viologen moiety was in the first reduced state, it became dominant at the electrode modified with AuCl4^[2-] when viologen moiety became the second reduced state. FT-IR measurement confirmed the formation of formic acid/formate ion at the PdCl4^[2-]/viologen-modified Si electrode.

収録刊行物

  • Chemistry letters

    Chemistry letters 41(3), 328-330, 2012-03-05

    Chemical Society of Japan

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