Highly Selective Sorption of Small Polar Molecules by a Nonporous Ionic Crystal of a Lacunary Keggin-type Heteropoly Anion and Alkali Metal Cations

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著者

    • MIURA Yu-ki
    • Graduate School of Environmental Science, Hokkaido University
    • KAMIYA Yuichi
    • Research Faculty of Environmental Earth Science, Hokkaido University

抄録

Cesium-potassium salt of the lacunary phosphotungstate Cs6.1K0.9[PW11O39), which is a non-porous ionic solid, absorbed only water and methanol, whereas larger alcohols (C ≥ 2) and hydrocarbons were completely excluded. Cs6.1K0.9[PW11O39] selectively removed water from water-ethanol mixed gas and was reusable by vacuum treatment at room temperature.

収録刊行物

  • Chemistry letters

    Chemistry letters 41(3), 331-333, 2012-03-05

    Chemical Society of Japan

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