一浴法および二浴法によって作製されたCu/Niナノオーダー多層めっき膜の耐摩耗性 The Wear Resistance Property of Cu/Ni Multilayer Films Prepared by Electrodeposition in Single and Dual Baths

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An abrasion wear tester was used to ascertain the difference between the wear resistances of Cu/Ni multilayer films that were prepared electrochemically using single or dual baths. The formation of oxide layers on the deposited layers and the containment of phosphorus in the Ni layers improved the films' wear resistance. For conditions in which phosphorus was contained and surface oxide layers were formed, the film prepared using a dual bath exhibited slightly higher wear resistance than the film prepared using a single bath. The difference in the wear resistances was regarded as caused by the difference in the degree of the film surfaces' exposure to air because the film was exposed directly to air during transfer between the two baths in the dual-bath method. Therefore, for the single-bath method, the exposure of Ni layers to air after electrodeposition of each layer produced higher wear resistance of the film. Detailed analysis of the oxidation state of the metal and the surface morphology of the films using an X-ray photoelectron spectroscope, a scanning electron microscope, and an atomic force microscope revealed that the smooth Ni oxide layer formed on the Ni layers contributes to improved wear resistance of the films.

収録刊行物

  • 表面技術 = The journal of the Surface Finishing Society of Japan

    表面技術 = The journal of the Surface Finishing Society of Japan 62(12), 681-685, 2011-12-01

    一般社団法人 表面技術協会

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各種コード

  • NII論文ID(NAID)
    10030476013
  • NII書誌ID(NCID)
    AN1005202X
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    09151869
  • NDL 記事登録ID
    023358214
  • NDL 請求記号
    Z17-291
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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