糖質由来のキラルテンプレートを用いた立体選択的炭素-炭素結合形成反応の開発 Some Stereoselective Carbon-carbon Bond-forming Reactions Realized by Using Sugar-derived Chiral Templates

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In this article, the authors summarize a variety of stereoselective carbon-carbon bond-forming reactions realized by the use of sugar-derived chiral templates, which have been one of the active concerns in the authors’ group in these fifteen years. Representative chiral templates prepared from D-glucose, D-galactose, or D-mannose are introduced first. Then, the utility of these templates for stereoselective carbon-carbon bond-forming reactions are outlined. These reactions include, 1)1,4-conjugate additions, 2)α-alkylations of esters, 3)Diels-Alder cycloadditions, 4)1,3-dipolar cycloadditions, and 5)α,α-dialkylation for the construction of an all-carbon asymmetric quaternary center. The use of a D-glucose derivative equipped with two bulky silyl ethers at C2 and C3 is emphasized throughout the article as the most effective chiral template.

収録刊行物

  • 有機合成化学協会誌

    有機合成化学協会誌 69(12), 1363-1374, 2011-12-01

    社団法人 有機合成化学協会

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被引用文献:  1件中 1-1件 を表示

各種コード

  • NII論文ID(NAID)
    10030480459
  • NII書誌ID(NCID)
    AN0024521X
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    00379980
  • NDL 記事登録ID
    023364651
  • NDL 請求記号
    Z17-256
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
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