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- 村上 陽一
- 東京工業大学 グローバルエッジ研究院
書誌事項
- タイトル別名
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- Development of Phase-Stable Photon Upconverters for Efficient Solar Energy Utilization
- タイヨウコウ コウコウリツ リヨウ ニ ムケタ ソウ アンテイ ナ ヒカリ アップコンバーター ノ カイハツ
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Photon upconversion based on triplet-triplet annihilation (TTA) of excited triplet molecules is drawing attention due to its applicability for weak incident light, possessing a potential for improving efficiencies of solar energy conversion devices. Since energy transfer between triplet levels of different molecules and TTA are based on the Dexter mechanism, inter-molecular collision is necessary and hence the majority of previous studies have been done with organic solvents, which are volatile and flammable. This paper presents the development and characterization of phase-stable photon upconverters fabricated with ionic liquids, which are room temperature molten salts with negligible vapor pressure and high thermal stability. The employed aromatic molecules, which are carrier of photo-created energies and are non-polar (or weakly polar) molecules, are found to be stable in the polar environment of ionic liquids, contrary to expectation. The mechanism of the stable solvation is proposed. The upconversion quantum yields are found to rapidly saturate as the excitation light power increases. An analytical model was developed and compared with the experimental data. It is shown that ionic liquids are not viscous media for the purpose of TTA-based upconversion.
収録刊行物
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- 日本伝熱学会論文集
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日本伝熱学会論文集 20 (2), 15-26, 2012
社団法人 日本伝熱学会
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詳細情報 詳細情報について
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- CRID
- 1390001204415149824
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- NII論文ID
- 10030483388
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- NII書誌ID
- AA11358679
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- COI
- 1:CAS:528:DC%2BC38Xht1antLjN
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- ISSN
- 18822592
- 09189963
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- NDL書誌ID
- 023727872
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可