Effects of the Hydrogen Absorption Conditions on the Hydrogen Embrittlement Behavior of Ni-Ti Superelastic Alloy
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- Yokoyama Ken'ichi
- Department of Materials Science and Engineering, Kyushu Institute of Technology
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- Nagaoka Akira
- Department of Materials Science and Engineering, Waseda University
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- Sakai Jun'ichi
- Department of Materials Science and Engineering, Waseda University Faculty of Science and Engineering, Waseda University
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The present study has investigated whether the hydrogen embrittlement behavior of Ni–Ti superelastic alloy can be changed by modifying the hydrogen absorption conditions. Upon immersion in H2SO4 or H3PO4 solution, the stress plateau due to the stress-induced martensite transformation becomes unclear and forms a gentle slope. In addition, the superelastic strain decreases with increasing immersion time. The peripheral part of the fracture surface of the immersed specimens is flat as usual, whereas the center part of the fracture surface is rough compared with that under other hydrogen absorption conditions reported previously. For the specimens immersed in H3PO4 solution, hydrogen thermal desorption tends to be observed at higher temperatures compared with the specimens immersed in H2SO4 solution. Moreover, for a longer immersion time, a second peak of hydrogen desorption is observed at a high temperature, indicating that the hydrogen states change with the hydrogen absorption conditions. The results of this study suggest that changing the hydrogen embrittlement behavior by modifying the hydrogen absorption conditions may enable the determination of the embrittlement mechanism of the alloy.
収録刊行物
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- ISIJ International
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ISIJ International 52 (2), 255-262, 2012
一般社団法人 日本鉄鋼協会
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詳細情報 詳細情報について
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- CRID
- 1390282681465087488
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- NII論文ID
- 10030746852
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- NII書誌ID
- AA10680712
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- ISSN
- 13475460
- 09151559
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
- KAKEN
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- 使用不可