The Micro-Flow Reaction System Featured the Liquid–Liquid Interface Created with Ternary Mixed Carrier Solvents in a Capillary Tube The Micro-Flow Reaction System Featured the Liquid-Liquid Interface Created with Ternary Mixed Carrier Solvents in a Capillary Tube

この論文にアクセスする

この論文をさがす

著者

抄録

A micro-flow reaction system was developed in which liquid–liquid interface was created based on the tube radial distribution of ternary mixed carrier solvents. The system was constructed from double capillary tubes having different inner diameters (100 and 250 μm i.d.). The smaller tube was inserted into the larger one through a T-type joint. The reaction of a protein with a fluorescence derivatizing reagent was adopted as a model. A water–acetonitrile mixture (3:1 volume ratio) including bovine serum albumin (hydrophilic) was delivered into the large tube from the inside through the small tube and an acetonitrile–ethyl acetate mixture (7:4 volume ratio) containing fluorescamine (hydrophobic) as a derivatizing reagent was delivered from the outside through the joint. Solutions were mixed through the double capillary tubes to promote ternary mixed carrier solvents (water–acetonitrile–ethyl acetate; 1:2:1 volume ratio). The liquid–liquid interface was created based on the tube radial distribution of ternary solvents in the larger tube. The derivatization reaction was performed in the larger, or reaction, tube in the micro-flow system. The fluorescence intensity of the fluorescamine-derivatized bovine serum albumin obtained by the system, which specifically included the kinetic liquid–liquid interface in the tube, was greater than that obtained through a batch reaction using a homogeneous solution of water–acetonitrile (1:2 volume ratio).

収録刊行物

  • Analytical sciences : the international journal of the Japan Society for Analytical Chemistry

    Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 28(5), 439-444, 2012-05-10

    社団法人 日本分析化学会

参考文献:  22件中 1-22件 を表示

  • <no title>

    GHANIM M. H.

    Talanta 85, 28, 2011

    被引用文献1件

  • <no title>

    HRNCIRIK P.

    Chem. Biochem. Eng. 24, 489, 2010

    被引用文献1件

  • <no title>

    YANG C.-G.

    Trends Anal. Chem. 29, 141, 2010

    被引用文献1件

  • <no title>

    GUIHEN E.

    Electrophoresis 31, 55, 2010

    被引用文献1件

  • <no title>

    TERABE S.

    Anal. Chem. 76, 240, 2004

    被引用文献1件

  • <no title>

    LUCY C. A.

    J. Chromatogr., A 1184, 81, 2008

    被引用文献1件

  • <no title>

    OTSUKA K.

    Chromatography 28, 1, 2007

    被引用文献1件

  • <no title>

    SMALL H.

    Adv. Colloid Interface Sci. 6, 237, 1976

    被引用文献1件

  • <no title>

    UMEHARA R.

    J. Sep. Sci. 32, 472, 2009

    被引用文献1件

  • <no title>

    JINNO N.

    Analyst. 136, 927, 2011

    被引用文献1件

  • <no title>

    JINNO N.

    Anal. Sci. 27, 259, 2011

    被引用文献1件

  • <no title>

    MURAKAMI M.

    Anal. Sci. 27, 793, 2011

    被引用文献1件

  • <no title>

    JINNO N.

    Talanta 79, 1348, 2009

    被引用文献1件

  • <no title>

    JINNO N.

    Anal. Sci. 26, 737, 2010

    被引用文献1件

  • <no title>

    FUJINAGA S.

    J. Sep. Sci. 34, 2833, 2011

    被引用文献1件

  • <no title>

    TJAHJONO M.

    Talanta 79, 856, 2009

    被引用文献1件

  • <no title>

    EL-SUBRUITI G.

    Prog. React. Kinet. Mech. 36, 73, 2011

    被引用文献1件

  • <no title>

    YAMADA Y. M. A.

    Chem.-A Eur. J. 16, 11311, 2010

    被引用文献1件

  • <no title>

    JOVANOVIC J.

    Ind. Eng. Chem. Res. 49, 2681, 2010

    被引用文献1件

  • <no title>

    TSUKAGOSHI K.

    Anal. Sci. 24, 1393, 2008

    被引用文献1件

  • <no title>

    MASUHARA Y.

    Chem. Lett. 40, 804, 2011

    被引用文献1件

  • <no title>

    TSUKAGOSHI K.

    Anal. Sci. 12, 525, 1996

    被引用文献1件

各種コード

  • NII論文ID(NAID)
    10030757261
  • NII書誌ID(NCID)
    AA10500785
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    09106340
  • NDL 記事登録ID
    023613875
  • NDL 請求記号
    Z54-F482
  • データ提供元
    CJP書誌  NDL  J-STAGE 
ページトップへ