Multielemental Elution Behavior of Metal Ions Adsorbed on Iminodiacetic Acid Chelating Resin by Using Hydrogen Peroxide as an Eluent

この論文にアクセスする

この論文をさがす

著者

    • SUMI Hidehiko SUMI Hidehiko
    • Department of Earth and Life Environmental Engineering, Graduate School of Advanced Technology and Science, The University of Tokushima
    • AKATSUKI Shinsuke
    • Department of Earth and Life Environmental Engineering, Graduate School of Advanced Technology and Science, The University of Tokushima
    • THUY Le Thi Xuan
    • Department of Earth and Life Environmental Engineering, Graduate School of Advanced Technology and Science, The University of Tokushima

抄録

In the present work, we investigated the multielemental elution behavior of metal ions absorbed on iminodiacetic acid (IDA) chelating resin by using hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) as an eluent. As a result, V(V), Mo(VI), W(VI), Nb(V) and Ta(V) were efficiently eluted by H<sub>2</sub>O<sub>2</sub>. In contrast, other metal ions were rarely recovered. The oxidation states of V(V), Mo(VI), and W(VI) were not changed through the H<sub>2</sub>O<sub>2</sub> eluting process, checked by X-ray photoelectron analysis. In addition, the UV-vis adsorption spectra and IR spectra of V(V), Mo(VI) and W(VI) in the H<sub>2</sub>O<sub>2</sub> eluent suggested the formation of metal-peroxo complexes through H<sub>2</sub>O<sub>2</sub> elution. The desorption of these metal ions from IDA functional groups is explained in term of destabilization along with the coordination of peroxo-ligands to the V(V)-, Mo(VI)- and W(VI)-IDA complexes, and a decrease in the adsorption capacity by electrostatic repulsion between dissociated carboxylic groups of IDA and the oxoanions in the neutral pH shown in 30 wt% H<sub>2</sub>O<sub>2</sub>. When this method was applied to the selective separation of V(V), Mo(VI) and W(VI) from other metals in an acid soluble fraction of fly-ash, 83.4 ± 2.5% of V(V), 88.1 ± 3.3% of Mo(VI), and 69.3 ± 5.4% of W(VI) were recovered in a 30 wt% H<sub>2</sub>O<sub>2</sub> eluent.

収録刊行物

  • Analytical sciences : the international journal of the Japan Society for Analytical Chemistry

    Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 28(5), 463-468, 2012-05-10

    社団法人 日本分析化学会

参考文献:  23件中 1-23件 を表示

  • <no title>

    ZHU Y.

    Bull. Chem. Soc. Jpn. 78, 659, 2005

    被引用文献1件

  • <no title>

    OLIVEIRA E. P.

    J. Anal. At. Spectrom. 26, 578, 2011

    被引用文献1件

  • <no title>

    ADHIKARI C. R.

    Chem. Lett. 36, 1254, 2007

    被引用文献1件

  • <no title>

    INUI T.

    Anal. Sci. 26, 1093, 2010

    被引用文献1件

  • <no title>

    YABUTANI T.

    Bull. Chem. Soc. Jpn. 74, 31, 2001

    被引用文献1件

  • <no title>

    YABUTANI T.

    Bull. Chem. Soc. Jpn. 72, 2253, 1999

    被引用文献1件

  • <no title>

    KON Y.

    Synthesis 7, 1092, 2011

    被引用文献1件

  • <no title>

    CHISHIRO T.

    Yuki Gosei Kagaku Kyokaishi 66, 1085, 2008

    被引用文献1件

  • <no title>

    CONNOR J. A.

    Advances in Inorganic Chemistry and Radiochemistry 6, 279, 1964

    被引用文献1件

  • <no title>

    TAMARU M.

    Bunseki Kagaku 53, 1435, 2004

    被引用文献1件

  • <no title>

    CHENG C. J.

    Anal. Chim. Acta 198, 173, 1987

    被引用文献1件

  • NIST X-ray Photoelectron Spectroscopy Database, NIST Standard Reference Database 20, Ver. 3.5

    National Institute of Standard and Technology (NIST USA)

    http://srdata.nist.gov/xps/Default.aspx

    被引用文献1件

  • <no title>

    SHELDON R. A.

    Metal-Catalyzed Oxidation of Organic Compounds 71, 1981

    被引用文献1件

  • <no title>

    REYNOLDS M. S.

    Inorg. Chem. 35, 2378, 1996

    被引用文献1件

  • <no title>

    KREINGOL'D S. U.

    Russ. J. Inorg. Chem. 25, 1355, 1980

    被引用文献1件

  • <no title>

    WON T.-J.

    Inorg. Chem. 33, 3804, 1994

    被引用文献1件

  • <no title>

    FUNAHASHI S.

    J. Coord. Chem. 3, 125, 1973

    被引用文献1件

  • <no title>

    LAGE P.

    Coord. Chem. Rev. 237, 77, 2003

    被引用文献1件

  • <no title>

    SCHWANE L. M.

    Inorg. Chem. 28, 3938, 1989

    被引用文献1件

  • <no title>

    MAHMOUD M. H. H.

    Anal. Sci. 10, 929, 1984

    被引用文献1件

  • <no title>

    TURNER D. R.

    Geochim. Cosmochim. Acta 45, 855, 1981

    被引用文献1件

  • JOGMEC Activities

    Japan Oil Gas and Metals National Corporation (JOGMEC)

    http://www.jogmec.go.jp/english/activities/stockpiling_metal/raremetals.html

    被引用文献1件

  • <no title>

    SOLDI T.

    Anal. Chim. Acta 323, 27, 1996

    被引用文献2件

各種コード

  • NII論文ID(NAID)
    10030757385
  • NII書誌ID(NCID)
    AA10500785
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    09106340
  • NDL 記事登録ID
    023613911
  • NDL 請求記号
    Z54-F482
  • データ提供元
    CJP書誌  NDL  J-STAGE 
ページトップへ