Physicochemical and Acid-base Properties of a Series of 2-Hydroxyethylammonium-based Protic Ionic Liquids

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Physicochemical properties such as a thermal behavior, ionic conductivity, viscosity and density, and acid-base properties of a new class of 2-hydroxyethylammonium-based protic ionic liquids (PILs) have been investigated. Thirty-six potential PILs were surveyed to find 32 salts with a melting point below 373 K. Among them, [(EtOH)<sub>n</sub>Et<sub>(3−n)</sub>NH<sup>+</sup>][TFS<sup>−</sup>] (Et, C<sub>2</sub>H<sub>5</sub>; <i>n</i> = 0 – 3) and [(EtOH)<sub>2</sub>EtNH<sup>+</sup>][X<sup>−</sup>] (X = TFS, trifluoromethanesulfonate; TFSA, bis(trifluoromethanesulfonyl)amide; NO<sub>3</sub>) were studied in terms of the Walden plots, molar volume and auto-protolysis reaction for effect of the number of 2-hydroxyethyl groups introduced in the cations and for dependence of the anion nature, respectively. With regard to [(EtOH)<sub>n</sub>Et<sub>(3−n)</sub>NH<sup>+</sup>][TFS<sup>−</sup>] (<i>n</i> = 0 – 3), the ion-ion interactions between cation-anion and cation-cation were enhanced with increasing the number of the 2-hydroxyethyl groups. In addition, the auto-protolysis constant <i>K</i><sub>s</sub> value for [(EtOH)<sub>2</sub>EtNH<sup>+</sup>][TFSA<sup>−</sup>] is smaller than that for TFS<sup>−</sup> based PIL, indicating that HTFSA behaves as a stronger acid than HTFS in the respective PIL. On the other hand, in [(EtOH)<sub>2</sub>EtNH<sup>+</sup>][NO<sub>3</sub><sup>−</sup>], the emf jump was rather small, which suggests that the proton of HNO<sub>3</sub> does not easily transfer to (EtOH)<sub>2</sub>EtN in the liquid state.

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  • Analytical sciences : the international journal of the Japan Society for Analytical Chemistry

    Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 28(5), 469-474, 2012-05-10

    社団法人 日本分析化学会

参考文献:  70件中 1-70件 を表示

  • <no title>

    BRENNECKE J. F. ed.

    Ionic Liquids IV, 2007

    被引用文献1件

  • <no title>

    KOEL M. ed.

    Ionic Liquids in Chemical Analysis, 2009

    被引用文献1件

  • <no title>

    WASSERSCHEID P. ed.

    Ionic Liquids in Sythesis 1 and 2, 2007

    被引用文献1件

  • <no title>

    OHNO H. ed.

    Electrochemical Aspects of Ionic Liquids, 2005

    被引用文献1件

  • <no title>

    HIRAO M.

    J. Electrochem. Soc. 147, 4168, 2000

    被引用文献1件

  • <no title>

    BELIERES J.-P.

    J. Phys. Chem. B 111, 4926, 2007

    被引用文献1件

  • <no title>

    BAUTISTA-MARTINEZ J. A.

    J. Phys. Chem. C 113, 12586, 2009

    被引用文献1件

  • <no title>

    ROBERT T.

    ECS Trans. 3, 71, 2007

    被引用文献1件

  • <no title>

    ROBERT T.

    J. Electrochem. Soc. 156, F115, 2009

    被引用文献1件

  • <no title>

    JOHANSSON K. M.

    Phys. Chem. Chem. Phys. 10, 2972, 2008

    被引用文献1件

  • <no title>

    KANZAKI R.

    Chem. Lett. 36, 684, 2007

    被引用文献1件

  • <no title>

    KANZAKI R.

    Anal. Sci. 24, 1347, 2008

    被引用文献1件

  • <no title>

    COULING D. J.

    Green Chem. 8, 82, 2006

    被引用文献1件

  • <no title>

    NOCKEMANN P.

    J. Phys. Chem. B 111, 5254, 2007

    被引用文献1件

  • <no title>

    FUJITA K.

    Chem. Commun. 4804, 2005

    被引用文献1件

  • <no title>

    FUJITA K.

    Biotechnol. Bioeng. 94, 1209, 2006

    被引用文献1件

  • <no title>

    FUJITA K.

    Biomacromolecules 8, 2080, 2007

    被引用文献1件

  • <no title>

    FUJITA K.

    Biopolymers 93, 1093, 2010

    被引用文献1件

  • <no title>

    COOPER E. R.

    Nature 430, 1012, 2004

    被引用文献1件

  • <no title>

    GORKE J.

    Biotechnol. Bioprocess Eng. 15, 40, 2010

    被引用文献1件

  • <no title>

    YUAN X.

    Fluid Phase Equilib. 257, 195, 2007

    被引用文献1件

  • <no title>

    GALAN SANCHEZ L. M.

    Trans.-ChemE, Part A, Chem. Eng. Res. Des. 85, 31, 2007

    被引用文献1件

  • <no title>

    CAMPER D.

    Ind. Eng. Chem. Res. 47, 8496, 2008

    被引用文献1件

  • <no title>

    KURNIA K. A.

    J. Chem. Thermodyn. 41, 1069, 2009

    被引用文献1件

  • <no title>

    MATTEDI S.

    J. Supercrit. Fluids 56, 224, 2011

    被引用文献1件

  • <no title>

    PINKERT A.

    Chem. Rev. 109, 6712, 2009

    被引用文献1件

  • <no title>

    PINKERT A.

    Ind. Eng. Chem. Res. 49, 11809, 2010

    被引用文献1件

  • <no title>

    CHOI H.-M.

    Ind. Eng. Chem. Res. 50, 2452, 2011

    被引用文献1件

  • <no title>

    PALIMKAR S. S.

    J. Org. Chem. 68, 9371, 2003

    被引用文献1件

  • <no title>

    FANG D.

    Appl. Catal., A 345, 158, 2008

    被引用文献1件

  • <no title>

    WANG Y.

    Catal. Commun. 9, 2475, 2008

    被引用文献1件

  • <no title>

    ZHAO Y.

    Catal. Commun. 10, 732, 2009

    被引用文献1件

  • <no title>

    YANG J.

    Catal. Commun. 11, 1200, 2010

    被引用文献1件

  • <no title>

    BICAK N.

    J. Mol. Liq. 116, 15, 2005

    被引用文献1件

  • <no title>

    GREAVES T. L.

    J. Phys. Chem. B 110, 22479, 2006

    被引用文献1件

  • <no title>

    COTA I.

    J. Phys. Chem. B 111, 12468, 2007

    被引用文献1件

  • <no title>

    YUAN X. L.

    J. Chem. Eng. Data 52, 596, 2007

    被引用文献1件

  • <no title>

    GREAVES T. L.

    J. Phys. Chem. B 112, 896, 2008

    被引用文献1件

  • <no title>

    KURNIA K. A.

    J. Chem. Thermodyn. 41, 517, 2009

    被引用文献1件

  • <no title>

    BURRELL G. L.

    Phys. Chem. Chem. Phys. 12, 1571, 2010

    被引用文献1件

  • <no title>

    ALVAREZ V. H.

    J. Chem. Eng. Data 55, 625, 2010

    被引用文献1件

  • <no title>

    PINKERT A.

    Phys. Chem. Chem. Phys. 13, 5136, 2011

    被引用文献1件

  • <no title>

    YOSHIZAWA-FUJITA M.

    Phys. Chem. Chem. Phys. 13, 13427, 2011

    被引用文献1件

  • <no title>

    KURNIA K. A.

    J. Solution Chem. 40, 818, 2011

    被引用文献1件

  • <no title>

    KAWAI K.

    Langmuir 27, 7353, 2011

    被引用文献1件

  • <no title>

    KURNIA K. A.

    J. Mol. Liq. 159, 211, 2011

    被引用文献1件

  • <no title>

    WU T.-Y.

    Electrochim. Acta 56, 7278, 2011

    被引用文献1件

  • <no title>

    FUKAYA Y.

    Green Chem. 9, 1155, 2007

    被引用文献1件

  • <no title>

    KHODADADI-MOGHADDAM M.

    Appl. Catal., A 341, 58, 2008

    被引用文献1件

  • <no title>

    KHODADADI-MOGHADDAM M.

    Monatsh. Chem. 140, 329, 2009

    被引用文献1件

  • <no title>

    ZHANG S.

    J. Phys. Chem. B 114, 3912, 2010

    被引用文献1件

  • <no title>

    WALDEN P.

    Physik Chem. 55, 207, 246, 1906

    被引用文献1件

  • <no title>

    BERNARD U. L.

    J. Phys. Chem. C 114, 20472, 2010

    被引用文献1件

  • <no title>

    STOIMENOVSKI J.

    Phys. Chem. Chem. Phys. 12, 10341, 2010

    被引用文献1件

  • <no title>

    YOSHIDA K.

    J. Phys. Chem. C 115, 18384, 2011

    被引用文献1件

  • <no title>

    SEKI S.

    J. Mol. Liq. 152, 9, 2010

    被引用文献1件

  • <no title>

    HAYES R.

    Phys. Chem. Chem. Phys. 13, 3237, 2011

    被引用文献1件

  • <no title>

    BRAUMAN J. I.

    J. Am. Chem. Soc. 91, 2126, 1969

    被引用文献1件

  • <no title>

    BRAUMAN J. I.

    J. Am. Chem. Soc. 93, 3911, 1971

    被引用文献1件

  • <no title>

    BRAUMAN J. I.

    J. Am. Chem. Soc. 93, 3914, 1971

    被引用文献1件

  • <no title>

    MEOT-NER M.

    J. Am. Chem. Soc. 113, 4448, 1991

    被引用文献1件

  • <no title>

    HUNTER E. P. L.

    J. Phys. Chem. Ref. Data 27, 413, 1998

    被引用文献1件

  • <no title>

    SONG X.

    J. Phys. Chem. B 116, 2801, 2012

    被引用文献1件

  • <no title>

    UMEBAYASHI Y.

    J. Comput. Chem., Jpn. 7, 125, 2008

    被引用文献1件

  • <no title>

    YOSHIZAWA M.

    Electrochem. Solid State Lett. 4, E25, 2001

    被引用文献4件

  • <no title>

    OHNO H.

    Solid State Ionics 154-155, 303, 2002

    被引用文献7件

  • <no title>

    YOSHIZAWA M.

    J. Am. Chem. Soc. 125, 15411, 2003

    被引用文献12件

  • <no title>

    THOMAZEAU C.

    J. Am. Chem. Soc. 125, 5264, 2003

    被引用文献6件

  • <no title>

    XU W.

    J. Phys. Chem. B 107, 6170, 2003

    被引用文献14件

  • <no title>

    KOPPEL I. A.

    J. Am. Chem. Soc. 116, 3047, 1994

    被引用文献3件

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  • NII論文ID(NAID)
    10030757409
  • NII書誌ID(NCID)
    AA10500785
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    09106340
  • NDL 記事登録ID
    023613975
  • NDL 請求記号
    Z54-F482
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