Fullerene Derivatives Having High LUMO Levels for the Usage in Organic Thin-film Photovoltaic Cells

  • Matsuo Yutaka
    Department of Chemistry, School of Science, The University of Tokyo

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  • 有機薄膜太陽電池に用いられる高いLUMO準位をもつフラーレン誘導体
  • ユウキ ハクマク タイヨウ デンチ ニ モチイラレル タカイ LUMO ジュンイ オ モツ フラーレン ユウドウタイ

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Abstract

This review article describes design of fullerene derivatives having high lowest unoccupied molecular orbital (LUMO) levels to obtain high open-circuit voltage in organic thin-film photovoltaic cells. Introduction of organic electron-donating groups onto fullerene and reduction of the size of π-electron conjugated system of fullerene effectively raise fullerene’s LUMO levels, affording high performance organic photovoltaic devices. Addition of the dihydromethano group as the smallest carbon addend to fullerene to obtain 56π-electron fullerene derivatives is likely a promising strategy in this research.

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