Catalytic Asymmetric Synthesis of Planar-Chiral Transition-Metal Complexes

• Arae Sachie

• Ogasawara Masamichi

  Catalysis Research Center, Hokkaido University

Bibliographic Information

Other Title

• 面不斉遷移金属錯体の触媒的不斉合成
• メン フセイ センイ キンゾク サクタイ ノ ショクバイテキ フセイ ゴウセイ

Abstract

Although “central chirality” based on stereogenic carbon atoms is arguably the most common chiral element in organic chemistry, chiral molecules devoid of stereogenic centers play important roles in stereoselective organic transformations. Among these chiral compounds with “non-centrochirality”, planar-chiral transition-metal complexes have been utilized as chiral ligands, chiral catalysts, or chiral building blocks in asymmetric synthesis. However, enantiomerically enriched forms of these compounds are primarily obtained by rather classical methods. Examples of catalytic enantioselective induction of planar-chirality in transition-metal species have been extremely rare and still a developing area in this field. In this review article, catalytic asymmetric synthesis of various “planar-chiral transition-metal complexes” are surveyed in a comprehensive manner.

Journal

• Journal of Synthetic Organic Chemistry, Japan

  Journal of Synthetic Organic Chemistry, Japan 70 (6), 593-605, 2012

  The Society of Synthetic Organic Chemistry, Japan

Keywords

• planar-chiral
• asymmetric synthesis
• transition-metal complex
• chiral catalyst
• enantioselective
• kinetic resolution
• metallocene
• η⁶-arene-chromium complex
• η⁴-diene-iron complex

Details

• CRID: 1390282680315560064
• NII Article ID: 10030765844
• NII Book ID: AN0024521X
• DOI: 10.5059/yukigoseikyokaishi.70.593
• COI: 1:CAS:528:DC%2BC38XovF2mtLc%3D
• ISSN: 18836526
• ISSN: 00379980
• NDL BIB ID: 023824577
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I023824577
• Web Site: https://www.jstage.jst.go.jp/article/yukigoseikyokaishi/70/6/70_593/_pdf
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed