Design and Synthesis of Thermo-Responsive Films with High Sensitivity: Effects of Primary Architectures of Diblock Copolymers and Conditions for Film Formation

• TAKISHITA Hirotaka

  Department of Macromolecular Science, Graduate School of Science, Osaka University

• KANAZAWA Arihiro

  Department of Macromolecular Science, Graduate School of Science, Osaka University

• KANAOKA Shokyoku

  Department of Macromolecular Science, Graduate School of Science, Osaka University

• AOSHIMA Sadahito

  Department of Macromolecular Science, Graduate School of Science, Osaka University

Bibliographic Information

Other Title

• 高感度温度応答性フィルムの創製<br/>—ブロックコポリマー構造設計およびフィルム作成条件の影響—
• 高感度温度応答性フィルムの創製 : ブロックポリマー構造設計およびフィルム作成条件の影響
• コウカンド オンド オウトウセイ フィルム ノ ソウセイ : ブロックポリマー コウゾウ セッケイ オヨビ フィルム サクセイ ジョウケン ノ エイキョウ

Abstract

Various block copolymers of an alicyclic vinyl ether with a stimuli-responsive vinyl ether were synthesized by living cationic polymerization in the presence of a weak Lewis base. The obtained copolymers had very narrow molecular weight distributions and could form free-standing films when they had an alicyclic segment of sufficient length. The design of the primary structures of the polymers and the control of the surface morphology were critical for controlling thermally responsive wettability transitions of the film surfaces.

Journal

• KOBUNSHI RONBUNSHU

  KOBUNSHI RONBUNSHU 69 (6), 305-308, 2012

  The Society of Polymer Science, Japan

Keywords

• Cationic Polymerization
• Stimuli-Responsive
• Film
• Contact Angle
• Block Copolymer

Details

• CRID: 1390282681502309376
• NII Article ID: 10030772993
• NII Book ID: AN00085011
• DOI: 10.1295/koron.69.305
• COI: 1:CAS:528:DC%2BC38Xht1Klu7bK
• ISSN: 18815685
• ISSN: 03862186
• NDL BIB ID: 023787366
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I023787366
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Disallowed