Iodide-promoted Deselenylation of β-Chloro- and β-Oxyselenides to Form Alkenes and Selenenyl Iodides

• Shohei Sase

  Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology

• Kazuaki Ebisawa

  Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology

• Kei Goto

  Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology

Abstract

Deselenylation reaction of β-chloro- and β-oxyselenides proceeded efficiently by treatment with tetrabutylammonium iodide (TBAI) to afford alkenes in good yields. It was established that selenenyl iodides were formed in these reactions. Catalytic transformation of β-chloro- and β-oxyselenides to alkenes was also developed.

Journal

• Chemistry Letters

  Chemistry Letters 41 (8), 766-768, 2012-07-21

  Oxford University Press (OUP)

Keywords

• General Chemistry

Details

• CRID: 1360002219111718144
• NII Article ID: 10030946954
• NII Book ID: AA00603318
• DOI: 10.1246/cl.2012.766
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/41/8/766/55639490/cl.2012.766.pdf
• Data Source:
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