Silane(silyl) and Bis(silyl)hydrido Manganese Complexes with Different Mn…H…Si Interaction : Observation of Gradual Si-H Bond Activation on the Metal Center

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著者

    • KOMURO Takashi
    • Department of Chemistry, Graduate School of Science, Tohoku University
    • OKAWARA Satoshi
    • Department of Chemistry, Graduate School of Science, Tohoku University
    • TOBITA Hiromi
    • Department of Chemistry, Graduate School of Science, Tohoku University

抄録

Three manganese–carbonyl complexes having a xanthene-based silane(silyl) or bis(silyl) chelate ligand were synthesized and characterized. The single-crystal X-ray analysis of these complexes demonstrated that an Si–H bond is sequentially activated on the metal according to ligand substitution of CO with xanthene-oxygen or η<sup>6</sup>-toluene.

収録刊行物

  • Chemistry letters

    Chemistry letters 41(8), 774-776, 2012-08-05

    公益社団法人 日本化学会

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各種コード

  • NII論文ID(NAID)
    10030947051
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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