From Thiopheneboroles to Boron-containing Conjugated Macromolecules via Electropolymerization

• HAYASHI Shotaro

  Department of Applied Chemistry, National Defense Academy

• KOIZUMI Toshio

  Department of Applied Chemistry, National Defense Academy

Abstract

Electropolymerization of thiophene-3-boroles was successfully carried out in the presence of BF₃-OEt₂ as roles of supporting electrolyte and lowering their oxidation potentials. The obtained polythiophenes having borole moieties showed broadening energy band due to the extended conjugated system via the borole side chain.

Journal

• Electrochemistry

  Electrochemistry 81 (5), 340-342, 2013

  The Electrochemical Society of Japan

Keywords

• Electropolymerization
• Borole
• Conjugated Polymers

Details

• CRID: 1390001206496101120
• NII Article ID: 10031151995
• NII Book ID: AN00151637
• DOI: 10.5796/electrochemistry.81.340
• ISSN: 21862451
• ISSN: 13443542
• NDL BIB ID: 024446261
• Web Site: http://id.ndl.go.jp/bib/024446261
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I024446261
• Web Site: https://www.jstage.jst.go.jp/article/electrochemistry/81/5/81_12-10-E50737/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Allowed