Electro-reductive Halogen-Deuterium Exchange and Methylation of Aryl Halides in Acetonitrile

• MITSUDO Koichi

  Division of Chemistry and Biotechnology, Graduate School of Natural Science and Technology, Okayama University

• OKADA Takahiro

  Division of Chemistry and Biotechnology, Graduate School of Natural Science and Technology, Okayama University

• SHIMOHARA Shuichi

  Division of Chemistry and Biotechnology, Graduate School of Natural Science and Technology, Okayama University

• MANDAI Hiroki

  Division of Chemistry and Biotechnology, Graduate School of Natural Science and Technology, Okayama University

• SUGA Seiji

  Division of Chemistry and Biotechnology, Graduate School of Natural Science and Technology, Okayama University

抄録

An electro-reductive halogen-deuterium exchange reaction in CD₃CN has been developed. Using 9-fluorenone as a mediator, the electro-reduction of several aryl halides proceeded smoothly to give the deuterated products selectively. A methylation reaction of aryl halides also proceeded under similar conditions.

収録刊行物

• Electrochemistry

  Electrochemistry 81 (5), 362-364, 2013

  公益社団法人　電気化学会

キーワード

• Electro-reduction
• Halogen-Deuterium Exchange
• Deuteriation
• Methylation

詳細情報

• CRID: 1390282681475473536
• NII論文ID: 10031152002
• NII書誌ID: AN00151637
• DOI: 10.5796/electrochemistry.81.362
• ISSN: 21862451
• ISSN: 13443542
• NDL書誌ID: 024446641
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I024446641
• Web Site: https://www.jstage.jst.go.jp/article/electrochemistry/81/5/81_12-11-E50754/_pdf
• 本文言語コード: en
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