Investigation of the Pathway for Intramolecular Electron Transfer in Anodic [2 + 2] Cycloaddition Reactions

• KAMIMURA Kazuya

  Department of Applied Biological Science, Tokyo University of Agriculture and Technology

• OKADA Yohei

  Department of Applied Biological Science, Tokyo University of Agriculture and Technology

• CHIBA Kazuhiro

  Department of Applied Biological Science, Tokyo University of Agriculture and Technology

Abstract

Intramolecular electron transfer is expected to play a key role in anodic [2 + 2] cycloaddition reactions. We synthesized 2-allyl-6-methoxy-1,2,3,4-tetrahydronaphthalene as an olefin nucleophile to study the [2 + 2] reaction, leading to the finding that the intramolecular electron transfer that completes the formation of cyclobutane rings occurs mainly through space rather than through bonds.

Journal

• Electrochemistry

  Electrochemistry 81 (5), 377-379, 2013

  The Electrochemical Society of Japan

Keywords

• Intramolecular Electron Transfer
• Anodic [2 + 2] Cycloaddition Reaction
• Radical Cation
• Olefin Nucleophile

Details

• CRID: 1390001206496100096
• NII Article ID: 10031152007
• NII Book ID: AN00151637
• DOI: 10.5796/electrochemistry.81.377
• ISSN: 21862451
• ISSN: 13443542
• NDL BIB ID: 024446838
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I024446838
• Web Site: https://www.jstage.jst.go.jp/article/electrochemistry/81/5/81_12-10-E50738/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• Abstract License Flag: Allowed